Carbon materials for catalysis - download pdf or read online

By Philippe Serp

ISBN-10: 047017885X

ISBN-13: 9780470178850

This is often the 1st entire ebook protecting all features of using carbonaceous fabrics in heterogeneous catalysis. It covers the practise and characterization of carbon helps and carbon-supported catalysts; carbon floor chemistry in catalysis; the outline of catalytic, photo-catalytic, or electro-catalytic reactions, together with the advance of latest carbon fabrics resembling carbon xerogels, aerogels, or carbon nanotubes; and new carbon-based fabrics in catalytic or adsorption procedures. this can be a top-rated reference for carbon, inorganic, and actual chemists, fabrics scientists and engineers, chemical engineers, and others.

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The mechanistic discussion of (the inconsistencies of) such a scheme is discussed elsewhere [24]. Here it is worth emphasizing that one portion of the authors’ argument, regarding the quinone–hydroquinone character of activated carbon, carbon black [233] and other carbon materials, has withstood the test of time remarkably well [232]. In addition to quinone groups, and to some extent to pyrones, which undoubtedly confer basicity to carbons, the possibility of existence of an oxygen-free, positively charged basic site on the carbon surface was acknowledged in elegant early studies by Rivin [235]: Ar + H+ = ArH+ ArH+ + O2 = Ar2+ + HO− 2 Ar2+ + 2HX = Ar2+ }2X− + 2H+ A zigzag carbene atom is a very promising candidate for this heretofore unidentified site; this is discussed in more detail elsewhere [80].

1965) 240. F. , Prentice Hall, Upper Saddle River, NJ, 1996. H. -D. F¨orsterling, Principles of Physical Chemistry: Understanding Molecules, Molecular Assemblies, Supramolecular Machines, Wiley, Chichester, UK, 2000. J. Steed, J. Atwood, Supramolecular Chemistry, Wiley, Chichester, UK, 2000. R. Radovic, in F. B´eguin, E. , Electrochemistry of Carbon Materials, Taylor & Francis, (CRC Press), Boca Raton, FL, in press. N. R. , Chemistry and Physics of Carbon, Vol. 29, Marcel Dekker: New York, 2004, p.

Lamb, K. R. Huffman, Nature 347 (1990) 354. [6] E. H. P. Boehm, H. Marsh, Pure Appl. Chem. 67 (1995) 473. I. W. Smith, The Physics and Chemistry of Materials, Wiley, New York, 2001. D. , Materials Science and Engineering: An Introduction, Wiley, New York, 1991. D. , Fundamentals of Materials Science and Engineering: An Interactive e-Text , Wiley, New York, 2001. L. Mantell, Carbon and Graphite Handbook , Interscience, New York, 1968. O. Pierson, Handbook of Carbon, Diamond and Fullerenes, Noyes Publications, Park Ridge, NJ, 1993.

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Carbon materials for catalysis by Philippe Serp


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